According to GDPR, the app developer is the "data controller" and thus ultimately responsible. Only in the case where Apple knowingly participated in unlawful behavior is it likely to be held accountable, and even then, in addition to the app developer. Obviously, if we are not talking about leaks from the actual App Store system (eg. Apple account logins and user data).
So while it sounds plausible, the legal framework is exactly not what you describe here — Apple can claim to want better protection for customers by not allowing third party apps, but EU rejects that (it can similarly extend to app store itself) and pushes for competitive landscape with DMA instead.
Couldn’t someone argue that they “knowingly participated“? Do you think they want that risk?
Nothing holds them from having designed this as an API that others can use where the user has permission toggles of what data they want to share with the LLM provider.