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Current LLM’s are based on multi-character tokens, which means they don’t know how to spell well. As a result, they are horrible at spelling games like this or, say, Hangman.
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Llama 3.3 worked but (as you said) struggled before arriving at the correct answer. The newer Gemma3 solved it efficiently:

  % ollama run gemma3:27b-it-qat 
  >>> Unscramble the following letters to form an English word: "M O O N S T A R E R"
  The unscrambled word is **ASTRONOMER**.
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gpt 4o got that one, but it's listed on lots of anagram sites so it's in the training data ;-)

But it failed badly when I tried a Norwegian word T U R V E I G L E N (utlevering), suggesting "uglelivert" which is not a word

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