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I can also recommend: "The Earth: An Intimate History" by Richard Fortey
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Second for John McPhee! Also Rising From the Plains.
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References to his books should carry a warning - something to the effect of:

"may inspire circuitous road trips involving many stops dangerously examining road-cuts on busy interstate highways"

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I would pay good money for a field guide/itinerary to accompany "Assembling California".

More directly related to the Green River, I found Wayne Ranney's "Carving Grand Canyon: Evidence, Theories, and Mystery" an accessible/engaging intro to deep geological mysteries.

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