Please don't.
I mean, I applaud your work. But let's also be honest (in the "tough love" sense): those are all toys with significant limitations that preclude anyone shipping any of them on an actual device to an actual consumer. I mean, your SOC (maybe a $2 one) surely already includes a SPI master and USB host!
Actual interconnects that solve real market problems have big boring spec books and competing implementations and silicon vendors. The application for PIO is basically limited to "I have to connect to this crazy old junk and no one makes the part I'd otherwise need".
How are you handling startup? The approach I had in mind was putting boot flash on the second channel with a separate CS pin from PSRAM and configuring that in OTP; any idea if that would work?