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I don't see how unexec would help with "decoupling the core from Emacs" since the core is written in Emacs Lisp.
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you could make a standalone executable. I was assuming that people didn't want to start emacs to run it. if its just because...emacs is just morally offensive and one doesn't even want it running under the covers, I dont how to help you.
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Emacs is needed because it provides Emacs Lisp.
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