Understanding what the C compiler generates is interesting, but without a corresponding intuition about the optimizer passes, such understanding is shallow and unlikely to be generalized to other problems in the future. You probably won’t even remember this the next time you debug another undefined behavior. On the other hand, if you were to know the optimizer passes employed by the compiler and could deduce this code from that, then it is a useful exercise to enhance your intuition about them.
I do agree that knowledge of compiler optimizations is really important to working this way, though you'll eventually pick them up anyway. I don't see much value in looking at -O0 or -Og disassembly. You want the strongest stuff the compiler can generate if you're going to do this, which is usually either -O3 or -Oz (both of which are strong in their own ways). -O0 disassembly is... just so much pain for so little gain. Besides, -O3 breaks more stuff anyway!
For someone without this level of experience (and who isn't interested in learning)... yeah, I can see why you'd want to do this another way. But if you've got the experience already, it's plenty fast enough.