(I'm going to skip over some basic stuff, and use some generalities)
Each Cone in the eye responds to a range of frequencies. This means that things that unless it's on the extreme low, or high, end of the frequencies that the human eye can discern you are going to have two, or all three, Cone types responding. The strength of those responses is what your brain uses to interpret the color that you see.
The real problem is that out in space there is no attenuation of sunlight, it's bright. Super crazy bright. It basically overloads all of your Cones, and Rods, all at once, there is no way for your brain to find a signal of "oh there's more higher wavelengths here so interpret bluer than normal" because all of the signals got maxed out. If you max out all of the signals, you get white. It doesn't matter that in absolute terms there's more blue, the lower and mid frequencies are also maxed out.
Mid-day sun in a clear sky is very white, in the 5k-6k color temperature range. It's hard to get a sense of how white it is because of how bright it is. In fact, the color temperature on the surface can be even higher than in outer-space!
Compare this to a "warm" light bulb, which is around 2.5K. Sunrise/sunset is also around that range.
Perhaps the "warm color" sun mindset comes from the only times that people can look directly at it. That is to say, around sunrise or sunset.