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Maximize is green. (Any chance you might be color blind?)
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Option-click green button does window maximise (normal click does full-screen)
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You can also hold ALT and press the green button to mazimze.
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The app still gets to decide though! Most programs do go full size with an alt+green click, but not all. A column-style Finder window, for example, seems to go taller but no wider.
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