In fact, stockfish's WDL is very rudimentary: it is a function of the centipawn evaluation of the position and the value of the remaining material.
See https://github.com/official-stockfish/Stockfish/blob/a6d055d...
Also, from a computer perspective, a >= 1 pawn is usually sufficient for a computer to win 100% of the time so it's not really interesting and says very little about whether a person could win 100% of the time.
Relatedly, there is an interesting thing that lc0 has been doing as well, where it takes the contempt concept even further, and can beat you with queens odd. https://lczero.org/blog/2024/12/the-leela-piece-odds-challen... It assumes it is better than you and that it shouldn't just give up because you might be up a knight, rook or even queen.