The SLS has already proven it can fly to lunar orbit and back on one single launch. In contrast, even if everything goes according to plan, Starship requires at least a dozen re-fueling flights while it hangs in orbit around the Earth to be able to then fly to the Moon.
Will one Starship launch, when it eventually works, be cheaper than SLS? Very likely. Will 12+ Starship launches + the time in orbit be cheaper than a single SLS launch? Much, much less likely.