It's possible but rare for systems to have 64-bit GPRs but a 32-bit address space. Examples I can think of include the Nintendo 64 (MIPS; apparently commercial games rarely actually used the 64-bit instructions, so the console's name was pretty much a misnomer), some Apple Watch models (standard 64-bit ARM but with a compiler ABI that made pointers 32 bits to save memory), and the ill-fated x32 ABI on Linux (same thing but on x86-64).
That said, even "32-bit" CPUs usually have some kind of support for 64-bit floats (except for tiny embedded CPUs).
Now you could build a weird CPU that has "more memory" than it has addressable width (the 8086 is kind of like this with segmentation and 8/16 bit) but if your CPU is 64 bit you're likely not to use anything less than 64 bit math in general (though you can get some tricks with multiple adds of 32 bit numbers packed).
But a 32 bit CPU can do all sorts of things with larger numbers, it's just that moving them around may be more time-consuming. After all, that's basically what MMX and friends are.
It would also process binary-coded decimal integers, as well as floating point.
"The two came up with a revolutionary design with 64 bits of mantissa and 16 bits of exponent for the longest-format real number, with a stack architecture CPU and eight 80-bit stack registers, with a computationally rich instruction set."