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On residential - lots of people don't want to get their hands dirty. For commercial - it's rarely worth doing in-house and in manufacturing / food industries getting it wrong can lead to fines / closure losing contracts, so it's not worth penny pinching.
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My biggest problem with a service like pest control is I can't tell what it does. I'm not talking about getting rid of a hornet nest or squirrels in the attic, I'm talking about the door-to-door salespeople who want you to subscribe to a quarterly sprinkling of some magic dust around your house. If I could get a trustworthy measurement like "number of 2x4s not destroyed by carpenter ants" or "sqft of siding not rotten because of nests" I would be a lot more open to it.
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For the d2d residential services, you're buying peace of mind and usually the provider will guartantee the service. E.g. if you see ants and you're not due a visit until next month, they'll drop in and sort it.
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I think you're assuming that there is no valuable/monetizable difference between a neophyte, and an experienced expert serving (and supported by) a solid organization.

Also, I don't know where you live, but the more powerful substances used by licensed pest control are regulated and aren't (legally) available to the general public. If you're willing to run a business model based on unlicensed use of controlled substances, there are more profitable options than pest control lol

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fumigating houses, pest control at commercial food facilities, commercial premises etc is a big dirty difficult job and involves expensive equipment and hazardous chemicals etc plus as OP noted requires exams before you can do it for 3rd parties
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