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Yeah, max CV charging voltage is ~14V, max charging C rate is ~0.2C, open circuit voltage at 100% is that 13.x range. And lead acids like to stay at 100% unlike Li-ion which likes 50% +/-30%, so "12V" ICE cars just use a bus voltage of 13-14V and wire the battery there. At any given moment, the car's "12V" bus voltage MUST be above 13.x and below 14.4(absolute max).

It's a bit perplexing that those lead acid systems are referred to as "12V" systems when that figure is effectively the 0% voltage, whereas 3.7V for single Li-ion cell is the 50% voltage.

e: also, ICE transients can be in kV range, coming from ignition mechanisms. I've heard that you can literally measure engine RPM by selecting 1/dt on an oscilloscope and dividing that by cylinder count.

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The nominal range for automotive systems is 10-16v. If you are designing anything for automotive use that doesn’t work reliably in that range, you are manufacturing problems for people.
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This. Most cars nowadays come with the so-called "smart" alternators that vary voltage wildly depending on the current driving conditions.

One minute you might be accelerating and the onboard voltage drops as the battery supplies most of electricity. Then, as you reach the crest of a hill and start engine-braking, the car frantically tries to convert all the available kinetic energy to electricity, raising the onboard voltage to quickly charge the battery.

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>This. Most cars nowadays come with the so-called "smart" alternators that vary voltage wildly depending on the current driving conditions.

Which in practice means that they do a very miserly job charging the battery and are a ton more sensitive to a battery being in less than tip top shape so you can expect your battery lifetime to go down.

But it's a "win" because they pushed the serp belt change outside of whatever interval the reviewers who calculate TCO care about and they saved .000003mph in the process.

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