They are extremely good at intersections, as you can use the skip pointers in clever ways to skip ahead and eliminate whole swathes of values. You can kinda do that with b-trees[1] as well, but skip lists can beat them out in many cases.
It's highly dependent on the shape of the data though. For random numbers, it's probably an even match, but for postings lists and the like (where skiplists are often used), they perform extremely well as these often have runs of semiconsecutive values being intersected.
[1] I'll argue that if you squint a bit, a skiplist arguably is a sort of degenerate b-tree.
Things like BSP trees are very good at intersections indeed, and have been used for things since time immemorial, but I think the skiplist/tree tradeoff is not that different in this domain.