The breeding blanket is entirely contained inside a vacuum vessel, so there isn't any oxygen to react with. Also, the are many blanket designs, but the lithium is never present in its elemental form (precisely because it would be very reactive), but in a stable chemical bond with some neutron multiplier (like lithium-lead alloys or beryllium ceramics). In some design the lithium is even immersed in the coolant itself, which is high pressure helium, so it's not going to ignite in any reasonable way.
reply> breeding blanket is entirely contained inside a vacuum vessel, so there isn't any oxygen to react with
replyWhen the vessel works. If the vessel breaches, that lithium could ignite. Note a showstopper. But I suppose a risk to be thought about by the engineers (probably not by policymakers).
Commonwealth Fusion Systems plan to use lithium in salt form FLiBe, a molten salt made from a mixture of lithium fluoride (LiF) and beryllium fluoride (BeF2). It does not violently react with air or water.
replyThere seems to be a number of different prototypes of blankets, but the average operating temperature seems to be 300-700C. Adding oxygen to some of these designs while that hot may cause metal burning. This said, many of them are ceramic designs and would likely resist combustion.
replyWith all that said, it seems to be way less 'dangerous' material than would be in your average nuclear reactor, making it more of an industrial accident versus a planet contaminating mess.