And they won't attempt a catch with the first V3 booster because it's not worth the risk. They can build a new booster every couple of months. It takes much longer to build the launch/catch tower, and they don't have any spare towers yet. A catastrophe during a booster/ship catch would set them back a year, so they'll only attempt a catch if they're confident it will succeed.
Super Heavy: 200000 to 280000 kg
Falcon 9 first stage (without Falcon Heavy side boosters): 25600 kg
That and there's no way for it to stand without a catch tower.