The pre-trained ones no (except some of the new ones which have post training data added to pre-training for some reason). The post-trained ones yes (at least all the ones I've seen).
Some of the niche ones I'm not sure about. Like the historical LLMs. I have not tested those yet.
For sure, as they are stochastic parrots. My question should have been: what are the odds a llm would react properly to those instruction, but I got lazy and asked if they "know" it, because I presumed most readers here do know how llms are working.