When I first went into the workplace, it took me a bit of time to adjust to the non-academic setting. You think differently, you work differently. I discovered and learned problem-solving skills that I was not taught in school. Frankly, though, I'm glad I was not taught those skills in school, because they are easy to learn in the workplace, especially if you have a solid theoretical grounding (something which is a lot harder to pick up on the job).
To the extent that generalized problem-solving is a real thing, I think it probably boils down to the ability to quickly internalize information and draw connections, which conventional schooling already focuses on anyway.