Ohio DOT's use of road salt would allow for fresh water to be provided for somewhere in the neighborhood of 160,000 people.
On one hand, that's nowhere near enough people; it's a small drop in a giant thirsty bucket of water consumption. So we'll still need salt mountains, salt re-distribution vessels, and/or other ways to deal with excess salt.
On the other hand, 160k is a lot of humans. So perhaps we should look into doing things like this anyway.
(But we probably won't. Ohio gets road salt primarily from a mine under Lake Erie that has a very conveniently-located terminus near downtown Cleveland. The mine directly loads trucks, freight trains, and ships...and it's near the point of use already. It's pretty efficient.)