If vacuum tubes had pins of copper, the glass-metal joining would have cracked very soon during normal usage cycles, and there would have been no vacuum left in the tube.
Real vacuum tubes and gas tubes had pins made of kovar, which is a Fe-Ni-Co alloy with a TCE matched to a certain composition of borosilicate glass.
The kovar pins were normally plated with nickel on their external parts, to enable soldering, because molten solder does not wet kovar.