The RTX 3090 in question was used from eBay, no way to return it. The RTX 6000 Pro is the "new card" in question here. The 3090s remain an interesting playground for testing things like VFIO passthrough for SlicerVM and other models whilst not interrupting people on the newer card.
In the end, the most stable fix I've found is to install the older proprietary driver and disable the GSP firmware. Have had no issues since.
So "clearly defective hardware" seems like it may not be quite correct. And the thing that kept me coming back - along with not having a suitable replacement - or having to gamble on eBay again was the reliability once it showed up in nvidia-smi.