Now you can just start a server with deno pretty easily and serve a website. But WebUI will actually also manage opening the browser window for you as well a make the communication between backend and frontend just like using a Webview or electron.
Outside making it so you don't have to call to open the link yourself, I'm still not sure what could be integrated in the scenario. Deno can integrate with WebView because the WebView APIs were designed to allow external applications to have full control of the session. CEF (the Electron-like) approach works because Deno packages CEF & the APIs as part of the app itself, having even more control of everything. Browsers are meant to be in control of themselves or the user, and have had a long history of fighting malware trying to act otherwise.