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Because there's already another 6 on the same main diagonal. This is an "X Sudoku" puzzle, which means that each main diagonal must have all 9 different numbers.
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All I've never done the diagonals before... oops.

https://imgur.com/a/Dfxf9CJ (before picking 2 / 6 / 7.)

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https://www.sudokuwiki.org/sudokux.aspx is a useful site. I'm personally a fan of the killer variety.

Its solver is interesting in showing the individual steps.

For the same puzzle, https://www.sudokuwiki.org/sudokux.aspx?bd=06039000804900150...

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if you like sudoku, you owe it to yourself to check out the "cracking the cryptic" youtube channel and get introduced to the delightful world of variant sudoku.
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Yeah, that Sudoku puzzle has multiple valid solutions, whereas the page only seems to accept a single one.
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There's an extra constraint on that one: the two main diagonals must both have nine different digits. That's what makes it a single-solution puzzle.
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