1. Set the elo of all CVs to 1000 elo
2. Randomly pair up CVs and compare. Winners gain elo, losers lose elo.
3. Repeat #2 for a few iterations, then remove bottom X% of CVs.
4. Repeat 2-3 until the amount of remaining CVs is small enough to do an exhaustive comparison.
I don't have a mathematical proof, but I suspect that this is a decent cost-effective approximation of comparing every pair (depending on the parameters)
Or compare each one to a reference set? Take 5 resumes of existing employees, rank all candidates against that set, maybe you get some useful level prediction into the bargain