Most modern digital synths have already caught onto this and run internally at much higher sampling rates even if their output gets downsampled, but sometimes you run across a vintage plugin that runs at the host audio rate and working in a higher sampling rate is audible.
Oversampling gives you headroom for aliases for the rest of the synth that is more vulnerable to it.
* Some people are still making this mistake, despite information on the (many) ways to do it the right way being widely and freely available!
There's some ways to do band-limited distortion but...they aren't nearly as widespread, easy, or universal as band-limited oscillators.
Ring modulation is funny though because you'd ideally want the sidebands to modulate down by default rather than filter them out, that's why you're using it.
192 for mixing and mastering can be useful especially if you're doing a lot of effects, especially anything that pitch shifts. But I've seen low quality phone-microphone recordings make it to the master; if you capture lightning in a bottle, it hardly matters what the settings were, what the microphone was, or anything else.