Once 1Password supports it when I make a new passkey I'll store it in whichever of 1Password and Apple Passwords is more convenient and periodically sync them up.
Meanwhile I simply make two passkeys. I've only run into I think two sites that supported passkeys but would not let me make two.
On most sites making a second passkey is as simply as going to your security settings, finding the passkey settings there, hitting the "add another passkey" link, and pointing your phone at the QR code it shows, and then on those phone choosing the password manager that you did not use for the first passkey.