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No it can't. To combust it needs ~ 500F. If you left it out uncovered in the open and allowed the it to vaporize with a spark nearby, it might explode, but thats not spontaneous combustion. Gasoline sitting in a sealed container wont spontaneously combust.
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Didn't everyone have one of those old mechanic friends who liked to put the cigarette out in the can of gas to scare the tourists?
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That is definitely one of those “it worked the first 50 times no problem” tricks.
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Gasoline doesn't do that. Perhaps you're thinking of the following?

What it does do is slowly polymerize, becoming useless as an ICE fuel in time, typically in a year or two. This is why backup generators should run on propane, which has no degradation mechanism.

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No, I'm thinking of improperly stored gasoline evaporating and combusting.
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