I can do it on command but never paid attention to how before.
It's basically "yawning manually". There's a couple different muscles activating at the same time, most irrelevant to the popping, I can't control them individually yet. (Probably learnable, if I practiced I could probably get the pop more efficiently.)
But yeah, just yawn real wide, that should do it.
A lot of stuff is learnable, like I couldn't move my ears but taught myself how to do it because I was bored.