This usually has similar (in practice) performance characteristics to LTE Advanced.
5G SA is an actual, end to end 5G network. The two biggest wins here for an end user are reduced latency (a big focus in 5G) and reduced power usage (the phone doesn’t need a simultaneous 4G connection).
They created an option to use just the 5G radio modem parts with 4G tower equipment to run them in the "Non-StandAlone" mode, so that telcos can start deploying 5G before even it matures. And the modem parts and their specs are called "5G New Radio", which is one of names of all time.
NSA is non stand alone meaning basically 4G with some 5G backwards compatible improvements.