If your electricity comes from hydro, solar, wind - yes. If your electricity comes from fossil fuels - best power plant efficiency 60% - then not really. In US fossil fuels generate 60% of all the electricity.
If your power comes from fossils it's already been shipped half way around the world and refined, so that should be included in any efficiency calculation.
90% * 60% = 54%, which is still way better than the most efficient internal combustion engines. So even in that case an EV is still better. Plus, it gets greener when the grid gets greener.