[0] I use KDE, but it's essentially true of all of them
[1] that is, they require the command line
But I was curious and looked up the process; it seems that Thunar can only temporarily mount a network drive. So it remains a good example of the kinds of things you can easily do in the UI in Windows or macOS and thus feel weirdly lacking in Linux.
I keep it installed on a secondary drive just-in-case but I haven't booted into it in months.
Really? In my experience you can go for pretty much anything and it will be more coherent and less buggy than the Windows shell.
Try Gnome or XFCE. As a bonus you'll be able to remap Caps Lock with ease.