A stronger type of reachability property is that a state is always reachable from every other state. This is useful in, for example, eventually-consistent systems where you want to know that your system always could converge to every replica having the same state, even though it never actually does converge unless all writes to the system stop. The article links to a post about how to specify & check those properties in TLA+ (it is possible!) but the way to do this is very much not ergonomic.

Editing to add "there exists a behavior where P is true" is probably meant to mean P is an arbitrary temporal formula. So you are correct that with the limited reachability property you identified, you can express the formula "there exists a behavior satisfying <>S". However, you cannot express anything other than simple formulas like that, not general temporal formulas.