I personally think that you _could_ use an LLM to catch these types of boundary case errors without having to port the _entire_ C++ codebase to Rust, but maybe pre-emptively porting to Rust now can catch some of these cases for cheaper than doing a full LLM sweep. Also more cynically, its a good benchmark lol.
I guess if you really believe in curve of LLM capabilities you should just use a language that has the best performance, safety, flexibility, and extensibility, since in the limit few/no people will actually read the code anyway. I think this ends up being Rust.
The other thing is just that rewriting some old human-written codebase in Rust probably immediately catches many bugs. It would be hard to prompt the AI to properly scan for such bugs itself, they're lazy when working in that modality.