Worth adding to this: there may also be code needed in the rust part (not just the llvm part) to enable support for a target triplet. There certainly will be for the OS and libc part of the triplet: what specific syscalls exist and should be used to implement the standard library on a particular flavour of BSD etc.

But even for the architecture part there can be differences. For example, my understanding is that a lot of the calling convention details need to be handled by the frontend in LLVM, leading rustc to duplicate logic from clang here. Things like varargs FFI with C code can be particularly gnarly.