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"ligation" is the verb-form (i.e. making something with/into ligatures).

I'm not sure however that the verb form makes all that much sense in the context the website uses it...

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English is great at exceptions, but I'm nearly sure anything ending in -ation is a noun. Ligation certainly is.

Ligation is (among other things) the act of applying a ligature. So it does make sense.

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Yes, technically it is a deverbal noun, but I couldn't put my finger on that term at the time
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Ration can be a verb.
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