MPTCP doesn’t use any specific ports. It’s an OSI layer higher than that. It’s part of the TCP protocol itself. So if your firewall routes TCP traffic of a specific port (eg HTTP) already then it’ll route MPTCP along with it too.
MPTCP is a protocol extension that requires cooperation by both peers and all middleboxes. So, if there is a Layer 7 firewall, or DPI/SPI, or TLS termination on the path, and it's not inclined to preserve the MPTCP options, then MPTCP will be disabled.