admin/admin is on a post-it stuck to the monitor because everyone we hire is perfectly capable of rooting a machine they have physical access to.
What is unique about your system using LetsEncrypt that you can't automate certbot to handle this task as it was designed and intended to be done?
Some PLCs run extremely expensive machines. Some machines can't afford to have their control systems stutter or fail because that can lead to physical damage and production outages of enormous proportions. A PLC that stops communicating because a certificate just expired is absolutely not acceptable in some plants.
Running certbot on a random PLC isn't happening.